ETHYL NITRITE
ETHYL NITRITE
Ethyl nitrite is prepared by the action
of sodium nitrite on a mixture of alcohol and sulphuric acid in the cold. In
the laboratory ethyl nitrite gas is conveniently generated by placing 20 litres
of 90 percent ethanolin a suitable vessel, diluting with 200 litres of water,
and while stirring, adding to the dilute alcoholic nitrosyl chloride.
Ethyl nitrite, b.p. 17°, is a colourless
or yellowish, clear, flammable, exceedingly volatile liquid with characteristic
pleasant, ethereal odour and burning, sweetish taste. It is slightly soluble in
water and decomposed by it; miscible with alcohol and ether. On keeping, it
gradually decomposes to an acid and oxides of nitrogen are formed.
Decomposition is rapid by air, light, and moisture.
Uses: Ethyl nitrite is used as diaphoretic and
cardiovascular drug. It may cause methemoglobinemia and hypotension and, in
high concentrations, narcosis.
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