ETHYL NITRITE

ETHYL NITRITE

Ethyl nitrite is prepared by the action of sodium nitrite on a mixture of alcohol and sulphuric acid in the cold. In the laboratory ethyl nitrite gas is conveniently generated by placing 20 litres of 90 percent ethanolin a suitable vessel, diluting with 200 litres of water, and while stirring, adding to the dilute alcoholic nitrosyl chloride.




Ethyl nitrite, b.p. 17°, is a colourless or yellowish, clear, flammable, exceedingly volatile liquid with characteristic pleasant, ethereal odour and burning, sweetish taste. It is slightly soluble in water and decomposed by it; miscible with alcohol and ether. On keeping, it gradually decomposes to an acid and oxides of nitrogen are formed. Decomposition is rapid by air, light, and moisture.



 Uses: Ethyl nitrite is used as diaphoretic and cardiovascular drug. It may cause methemoglobinemia and hypotension and, in high concentrations, narcosis.



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